If the line away from the cab is getting pressure, then yes, find out where on the MCV it goes to. You may be right, it could have two way flow and maybe just needs turning on. Have you checked the tool control options in the monitor?
If you were starting from scratch and fitting two way aux for a thumb, you would simply run the two lines into the two ports on the fourth valve.
Is the crossover line correct? I would say it looks like a pretty kosher installation, probably done by a Cat dealer, so you would have to assume it is correct for what it was designed for.
I have played with tool control a bit but all i can do is select 1 thru 5 and all of them just say AUX. Non says the name of a attachment. I tried 2 different passwords but non get me any further then selecting 1 thru 5. My manual don't show any more then how to select tool and tells me to contact dealer. I have searched this forum and found other cat machines having more menus but i can not find them in my machine. As of right now "no tool" is selected and that is how i got the line to pressurize pushing on the peddle sliding around the floor. Maybe next time i will try a video to show just what i see and just what happens with what. Maybe that make life easier.