Ok heres a more technical description of why metal is brittle at cold temps. Now the molecular makeup of steels means that the atoms are formed in lattices, large blocks of these lattices make crystals, now when a your steel structural member is loaded, the metal flexes.
Now above glass transition temperature, the metal behaves like we mostly know it, that is can bend and does not fracture like a ceramic does. If however the metal is below the glass transition temperature, the metal will act structurally like a ceramic, that is as it is loaded it can fail with no or little warning. The ultimate strength, of any metal at below glass transition temperature is less than its normal ultimate strength.
Hope this is of interest
Cheers Alex