I can see from the photos you've had heat on it, but it doesn't look like too much judging by the colour of the paint. Try heating the "ears" of the bucket until they are almost red-hot then spray all around the exposed parts of the pin and down the securing bolt hole with penetrating fluid. That might well loosen it.
If not - plan B. Take the grease nipple out of the inside end of the pin, get a good 50 or 100-ton hydraulic jack (one that will work on its side - a lot won't) Get the jack in between the end of the pin and the bucket, heat the bejasus out of the 2 ears until they're almost red-hot, put some serious weight on with the jack then finally beat the hell out of the outside ear of the bucket to jar the pin loose.
If neither of the above work - thermic lance through the middle of the pin.