To vac the system you should open both the high and low valves on your gauges. Vac for an hour minimum then close off your valves. Your vac reading should maintain for a minimum of 45 minutes to ensure there isn't. any leaks. Purge your freon line then open the low valve only (the high valve shouldn't be touched throughout the rest of the filling process). When doing the initial fill with the engine off (that's the way I do it) , notice the gauge readings once it levels off.........the high and low readings should be exact or close which indicates a proper set for the expansion valve........in other words it should be functioning. Start the engine, a/c on, high blower speed with recirc on if you have that. 1500 rpm is good for filling. Check the ambient temp according to a chart, then crack open your low valve and let the system take freon in 50 psi increments (again, this is the way I do it) waiting a few minutes between 50 psi charges. Watch your vent temp........ideal is 35-45 degrees which in a mini you won't get. Get the high side to the reading on the chart......it should be around 7 times the low reading.....in other words, if the low is 30 psi, the high should be around 210 psi on an average system. Look for a vent temp within the specked range.
This is basic steps; I haven't used a measured load for 30 years...........it's a feel thing for me. There is always a system that just has to be different and out of the normal.
Before you even start this, you really need to pinch off the water flow to your heater core FIRST. The shutoff valves are usually crap and don't seal worth a dam. Even slight flow through the valve to the heater core can make a 10–15-degree difference in your air temp.